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Sulfur is a mineral component found in only in these sedimentary rock layers : sandstone, limestone, claystone, chalk, chert, shale and conglomerate.
It can be used for advanced medicine purposes: Honey-Sulfur reed poultice or Honey-Sulfur linen poultice.
Another usage is for making Blasting powder, a component of Ore blasting bombs.
Possible rocks for sulfur ore
Sometimes sulfur can appear in surface deposits bits like copper or coal.
Sulfur bits indicating a deposit